{"id":2380,"date":"2025-02-18T23:12:09","date_gmt":"2025-02-18T15:12:09","guid":{"rendered":"https:\/\/www.51malin.com\/index.php\/archives\/2380"},"modified":"2025-02-18T23:12:09","modified_gmt":"2025-02-18T15:12:09","slug":"1-%e5%bc%82%e4%b8%81%e5%9f%ba-2-%e7%94%b2%e5%9f%ba%e5%92%aa%e5%94%91%e4%bd%9c%e4%b8%ba%e6%9c%89%e6%9c%ba%e5%90%88%e6%88%90%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e5%8f%8d%e5%ba%94%e6%9c%ba%e7%90%86","status":"publish","type":"post","link":"https:\/\/www.51malin.com\/index.php\/archives\/2380","title":{"rendered":"1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\u4f5c\u4e3a\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\u7684\u53cd\u5e94\u673a\u7406\u53ca\u6027\u80fd\u7814\u7a76"},"content":{"rendered":"

\u5f15\u8a00<\/h3>\n
1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\uff081-Isobutyl-2-methylimidazolium\uff0c\u7b80\u79f0IBMI\uff09\u4f5c\u4e3a\u4e00\u79cd\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\uff0c\u5728\u8fd1\u5e74\u6765\u7684\u7814\u7a76\u4e2d\u9010\u6e10\u5d2d\u9732\u5934\u89d2\u3002\u5b83\u4e0d\u4ec5\u5177\u6709\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u8fd8\u5728\u591a\u79cd\u53cd\u5e94\u7c7b\u578b\u4e2d\u8868\u73b0\u51fa\u72ec\u7279\u7684\u4f18\u52bf\u3002\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u666e\u53ca\uff0c\u5bfb\u627e\u9ad8\u6548\u3001\u73af\u4fdd\u7684\u50ac\u5316\u5242\u6210\u4e3a\u5316\u5b66\u7814\u7a76\u7684\u91cd\u8981\u65b9\u5411\u3002IBMI\u4f5c\u4e3a\u4e00\u79cd\u79bb\u5b50\u6db2\u4f53\uff0c\u5176\u72ec\u7279\u7684\u7ed3\u6784\u548c\u6027\u8d28\u4f7f\u5176\u5728\u6709\u673a\u5408\u6210\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n
\u672c\u6587\u5c06\u6df1\u5165\u63a2\u8ba81-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\u4f5c\u4e3a\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\u7684\u53cd\u5e94\u673a\u7406\u53ca\u5176\u6027\u80fd\u8868\u73b0\u3002\u6211\u4eec\u5c06\u4ece\u5176\u57fa\u672c\u7ed3\u6784\u548c\u7269\u7406\u5316\u5b66\u6027\u8d28\u5165\u624b\uff0c\u9010\u6b65\u5206\u6790\u5176\u5728\u4e0d\u540c\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u673a\u5236\uff0c\u5e76\u7ed3\u5408\u56fd\u5185\u5916\u65b0\u7684\u7814\u7a76\u6210\u679c\uff0c\u5c55\u793a\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u6f5c\u529b\u3002\u6587\u7ae0\u8fd8\u5c06\u901a\u8fc7\u5bf9\u6bd4\u5b9e\u9a8c\u6570\u636e\uff0c\u63a2\u8ba8IBMI\u4e0e\u5176\u4ed6\u5e38\u89c1\u50ac\u5316\u5242\u7684\u4f18\u52a3\uff0c\u5e2e\u52a9\u8bfb\u8005\u66f4\u597d\u5730\u7406\u89e3\u5176\u4f18\u52bf\u548c\u5c40\u9650\u6027\u3002<\/p>\n

1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\u7684\u57fa\u672c\u7ed3\u6784\u4e0e\u7269\u7406\u5316\u5b66\u6027\u8d28<\/h3>\n
1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\uff08IBMI\uff09\u662f\u4e00\u79cd\u57fa\u4e8e\u54aa\u5511\u73af\u7684\u79bb\u5b50\u6db2\u4f53\uff0c\u5176\u5206\u5b50\u7ed3\u6784\u7531\u4e24\u4e2a\u5173\u952e\u90e8\u5206\u7ec4\u6210\uff1a\u54aa\u5511\u9633\u79bb\u5b50\u548c\u70f7\u57fa\u94fe\u3002\u5177\u4f53\u6765\u8bf4\uff0cIBMI\u7684\u9633\u79bb\u5b50\u90e8\u5206\u4e3a1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\uff0c\u9634\u79bb\u5b50\u90e8\u5206\u901a\u5e38\u4e3a\u5364\u7d20\u79bb\u5b50\uff08\u5982\u6c2f\u79bb\u5b50\u3001\u6eb4\u79bb\u5b50\uff09\u6216\u5176\u4ed6\u529f\u80fd\u6027\u9634\u79bb\u5b50\uff08\u5982\u516d\u6c1f\u78f7\u9178\u6839\uff09\u3002\u8fd9\u79cd\u7ed3\u6784\u8d4b\u4e88\u4e86IBMI\u4e00\u7cfb\u5217\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u4f7f\u5176\u5728\u6709\u673a\u5408\u6210\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

1. \u5206\u5b50\u7ed3\u6784<\/h4>\n
IBMI\u7684\u5206\u5b50\u7ed3\u6784\u53ef\u4ee5\u8868\u793a\u4e3a\uff1a<\/p>\n
[
\ntext{C}6text{H}<\/em>{10}text{N}_2^+ cdot X^-
\n]<\/p>\n
\u5176\u4e2d\uff0c\u9633\u79bb\u5b50\u90e8\u5206\u4e3a1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\uff0c\u9634\u79bb\u5b50\u90e8\u5206\u4e3a(X^-)\u3002\u54aa\u5511\u73af\u4e0a\u7684\u6c2e\u539f\u5b50\u5e26\u6709\u6b63\u7535\u8377\uff0c\u800c\u9634\u79bb\u5b50\u5219\u5e73\u8861\u4e86\u6574\u4e2a\u5206\u5b50\u7684\u7535\u8377\u3002\u54aa\u5511\u73af\u7684\u5b58\u5728\u4f7f\u5f97IBMI\u5177\u6709\u826f\u597d\u7684\u914d\u4f4d\u80fd\u529b\u548c\u9178\u78b1\u6027\uff0c\u80fd\u591f\u4e0e\u591a\u79cd\u53cd\u5e94\u7269\u53d1\u751f\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n

2. \u7269\u7406\u6027\u8d28<\/h4>\n
IBMI\u4f5c\u4e3a\u4e00\u79cd\u79bb\u5b50\u6db2\u4f53\uff0c\u5177\u6709\u4ee5\u4e0b\u663e\u8457\u7684\u7269\u7406\u6027\u8d28\uff1a<\/p>\n
\n
\n
\u7194\u70b9\u4f4e<\/strong>\uff1a\u5927\u591a\u6570IBMI\u7684\u7194\u70b9\u4f4e\u4e8e100\u00b0C\uff0c\u751a\u81f3\u6709\u4e9b\u54c1\u79cd\u53ef\u4ee5\u5728\u5ba4\u6e29\u4e0b\u5448\u6db2\u6001\u3002\u8fd9\u4e00\u7279\u6027\u4f7f\u5f97IBMI\u5728\u5e38\u6e29\u4e0b\u5373\u53ef\u4f5c\u4e3a\u6eb6\u5242\u6216\u50ac\u5316\u5242\u4f7f\u7528\uff0c\u907f\u514d\u4e86\u9ad8\u6e29\u64cd\u4f5c\u5e26\u6765\u7684\u80fd\u6e90\u6d88\u8017\u548c\u526f\u53cd\u5e94\u3002<\/p>\n<\/li>\n
\n
\u70ed\u7a33\u5b9a\u6027\u9ad8<\/strong>\uff1aIBMI\u5177\u6709\u8f83\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u80fd\u591f\u5728\u8f83\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u4fdd\u6301\u5176\u5316\u5b66\u7ed3\u6784\u4e0d\u53d8\u3002\u8fd9\u4f7f\u5f97\u5b83\u5728\u9ad8\u6e29\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u4e0d\u6613\u5206\u89e3\u6216\u5931\u6d3b\u3002<\/p>\n<\/li>\n
\n
\u6eb6\u89e3\u6027\u5f3a<\/strong>\uff1aIBMI\u5bf9\u591a\u79cd\u6709\u673a\u5316\u5408\u7269\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u6027\uff0c\u5c24\u5176\u662f\u6781\u6027\u8f83\u5f3a\u7684\u5316\u5408\u7269\u3002\u8fd9\u4e00\u7279\u6027\u4f7f\u5f97\u5b83\u5728\u591a\u76f8\u50ac\u5316\u53cd\u5e94\u4e2d\u80fd\u591f\u6709\u6548\u5730\u4fc3\u8fdb\u53cd\u5e94\u7269\u7684\u6df7\u5408\u548c\u4f20\u8d28\uff0c\u63d0\u9ad8\u53cd\u5e94\u6548\u7387\u3002<\/p>\n<\/li>\n
\n
\u4f4e\u6325\u53d1\u6027<\/strong>\uff1a\u4e0e\u4f20\u7edf\u6709\u673a\u6eb6\u5242\u76f8\u6bd4\uff0cIBMI\u7684\u6325\u53d1\u6027\u6781\u4f4e\uff0c\u51e0\u4e4e\u4e0d\u4f1a\u5728\u5e38\u6e29\u4e0b\u84b8\u53d1\u3002\u8fd9\u4e00\u7279\u70b9\u4e0d\u4ec5\u51cf\u5c11\u4e86\u6eb6\u5242\u635f\u5931\uff0c\u8fd8\u964d\u4f4e\u4e86\u5bf9\u73af\u5883\u7684\u6c61\u67d3\u98ce\u9669\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5b66\u7684\u8981\u6c42\u3002<\/p>\n<\/li>\n
\n
\u53ef\u8c03\u8282\u7684\u6781\u6027<\/strong>\uff1a\u901a\u8fc7\u6539\u53d8\u9634\u79bb\u5b50\u79cd\u7c7b\uff0c\u53ef\u4ee5\u8c03\u8282IBMI\u7684\u6781\u6027\u548c\u4eb2\u758f\u6c34\u6027\u3002\u4f8b\u5982\uff0c\u4f7f\u7528\u516d\u6c1f\u78f7\u9178\u6839\u4f5c\u4e3a\u9634\u79bb\u5b50\u65f6\uff0cIBMI\u7684\u6781\u6027\u8f83\u4f4e\uff0c\u9002\u5408\u7528\u4e8e\u975e\u6781\u6027\u53cd\u5e94\u4f53\u7cfb\uff1b\u800c\u4f7f\u7528\u6c2f\u79bb\u5b50\u6216\u6eb4\u79bb\u5b50\u65f6\uff0cIBMI\u7684\u6781\u6027\u8f83\u9ad8\uff0c\u9002\u5408\u7528\u4e8e\u6781\u6027\u53cd\u5e94\u4f53\u7cfb\u3002<\/p>\n<\/li>\n<\/ul>\n
3. \u5316\u5b66\u6027\u8d28<\/h4>\n
IBMI\u7684\u5316\u5b66\u6027\u8d28\u4e3b\u8981\u4f53\u73b0\u5728\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\uff1a<\/p>\n
\n
\n
\u9178\u78b1\u6027<\/strong>\uff1a\u54aa\u5511\u73af\u4e0a\u7684\u6c2e\u539f\u5b50\u5177\u6709\u4e00\u5b9a\u7684\u78b1\u6027\uff0c\u80fd\u591f\u4e0e\u9178\u6027\u7269\u8d28\u53d1\u751f\u8d28\u5b50\u5316\u53cd\u5e94\u3002\u6b64\u5916\uff0cIBMI\u8fd8\u53ef\u4ee5\u901a\u8fc7\u8c03\u8282\u9634\u79bb\u5b50\u79cd\u7c7b\u6765\u6539\u53d8\u5176\u9178\u78b1\u6027\u3002\u4f8b\u5982\uff0c\u4f7f\u7528\u9178\u6027\u9634\u79bb\u5b50\uff08\u5982BF4^-\uff09\u65f6\uff0cIBMI\u8868\u73b0\u51fa\u8f83\u5f3a\u7684\u9178\u6027\uff0c\u80fd\u591f\u4fc3\u8fdb\u9178\u50ac\u5316\u7684\u53cd\u5e94\uff1b\u800c\u4f7f\u7528\u78b1\u6027\u9634\u79bb\u5b50\uff08\u5982OH^-\uff09\u65f6\uff0cIBMI\u5219\u8868\u73b0\u51fa\u8f83\u5f3a\u7684\u78b1\u6027\uff0c\u9002\u7528\u4e8e\u78b1\u50ac\u5316\u7684\u53cd\u5e94\u3002<\/p>\n<\/li>\n
\n
\u914d\u4f4d\u80fd\u529b<\/strong>\uff1a\u54aa\u5511\u73af\u4e0a\u7684\u6c2e\u539f\u5b50\u5177\u6709\u8f83\u5f3a\u7684\u914d\u4f4d\u80fd\u529b\uff0c\u80fd\u591f\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\u3002\u8fd9\u4e00\u7279\u6027\u4f7f\u5f97IBMI\u5728\u91d1\u5c5e\u50ac\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u52a9\u50ac\u5316\u4f5c\u7528\uff0c\u80fd\u591f\u6709\u6548\u4fc3\u8fdb\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4e2d\u5fc3\u4e0e\u53cd\u5e94\u7269\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n<\/li>\n
\n
\u6297\u6c27\u5316\u6027<\/strong>\uff1aIBMI\u5177\u6709\u8f83\u597d\u7684\u6297\u6c27\u5316\u6027\uff0c\u80fd\u591f\u5728\u7a7a\u6c14\u4e2d\u957f\u65f6\u95f4\u7a33\u5b9a\u5b58\u5728\u800c\u4e0d\u88ab\u6c27\u5316\u3002\u8fd9\u4e00\u7279\u6027\u4f7f\u5f97\u5b83\u5728\u7a7a\u6c14\u654f\u611f\u7684\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u51cf\u5c11\u4e86\u5bf9\u60f0\u6027\u6c14\u4f53\u4fdd\u62a4\u7684\u9700\u6c42\u3002<\/p>\n<\/li>\n<\/ul>\n
1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\u4f5c\u4e3a\u50ac\u5316\u5242\u7684\u53cd\u5e94\u673a\u7406<\/h3>\n
1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\uff08IBMI\uff09\u4f5c\u4e3a\u4e00\u79cd\u9ad8\u6548\u7684\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\uff0c\u5176\u50ac\u5316\u673a\u5236\u4e0e\u5176\u72ec\u7279\u7684\u5206\u5b50\u7ed3\u6784\u5bc6\u5207\u76f8\u5173\u3002IBMI\u7684\u54aa\u5511\u73af\u548c\u70f7\u57fa\u94fe\u8d4b\u4e88\u4e86\u5b83\u591a\u79cd\u50ac\u5316\u529f\u80fd\uff0c\u80fd\u591f\u5728\u4e0d\u540c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\u53d1\u6325\u4e0d\u540c\u7684\u4f5c\u7528\u3002\u4e3a\u4e86\u66f4\u597d\u5730\u7406\u89e3IBMI\u7684\u50ac\u5316\u673a\u7406\uff0c\u6211\u4eec\u53ef\u4ee5\u5c06\u5176\u5206\u4e3a\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\u8fdb\u884c\u8ba8\u8bba\uff1a\u8d28\u5b50\u8f6c\u79fb\u3001\u914d\u4f4d\u50ac\u5316\u3001\u6c22\u952e\u4f5c\u7528\u4ee5\u53ca\u534f\u540c\u6548\u5e94\u3002<\/p>\n
1. \u8d28\u5b50\u8f6c\u79fb\u673a\u5236<\/h4>\n
IBMI\u7684\u54aa\u5511\u73af\u4e0a\u542b\u6709\u4e24\u4e2a\u6c2e\u539f\u5b50\uff0c\u5176\u4e2d\u4e00\u4e2a\u6c2e\u539f\u5b50\u5e26\u6709\u6b63\u7535\u8377\uff0c\u53e6\u4e00\u4e2a\u6c2e\u539f\u5b50\u5219\u5177\u6709\u4e00\u5b9a\u7684\u78b1\u6027\u3002\u8fd9\u79cd\u7ed3\u6784\u4f7f\u5f97IBMI\u80fd\u591f\u901a\u8fc7\u8d28\u5b50\u8f6c\u79fb\u673a\u5236\u53c2\u4e0e\u53cd\u5e94\u3002\u5177\u4f53\u6765\u8bf4\uff0cIBMI\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u4e24\u79cd\u65b9\u5f0f\u4fc3\u8fdb\u8d28\u5b50\u8f6c\u79fb\uff1a<\/p>\n
\n
\n
\u9178\u50ac\u5316<\/strong>\uff1a\u5f53IBMI\u4f5c\u4e3a\u9178\u6027\u50ac\u5316\u5242\u65f6\uff0c\u54aa\u5511\u73af\u4e0a\u7684\u6c2e\u539f\u5b50\u53ef\u4ee5\u63a5\u53d7\u8d28\u5b50\uff0c\u5f62\u6210\u8d28\u5b50\u5316\u7684\u54aa\u5511\u9633\u79bb\u5b50\u3002\u8fd9\u79cd\u8d28\u5b50\u5316\u7684\u54aa\u5511\u9633\u79bb\u5b50\u80fd\u591f\u6709\u6548\u5730\u6fc0\u6d3b\u53cd\u5e94\u7269\u4e2d\u7684\u4eb2\u6838\u8bd5\u5242\uff0c\u4fc3\u4f7f\u5176\u4e0e\u4eb2\u7535\u8bd5\u5242\u53d1\u751f\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u5728\u916f\u5316\u53cd\u5e94\u4e2d\uff0cIBMI\u53ef\u4ee5\u901a\u8fc7\u8d28\u5b50\u5316\u7fa7\u9178\u5206\u5b50\uff0c\u964d\u4f4e\u5176pKa\u503c\uff0c\u4ece\u800c\u52a0\u901f\u7fa7\u9178\u4e0e\u9187\u7684\u53cd\u5e94\u3002<\/p>\n<\/li>\n
\n
\u78b1\u50ac\u5316<\/strong>\uff1a\u5f53IBMI\u4f5c\u4e3a\u78b1\u6027\u50ac\u5316\u5242\u65f6\uff0c\u54aa\u5511\u73af\u4e0a\u7684\u6c2e\u539f\u5b50\u53ef\u4ee5\u63d0\u4f9b\u8d28\u5b50\uff0c\u4fc3\u4f7f\u53cd\u5e94\u7269\u4e2d\u7684\u4eb2\u7535\u8bd5\u5242\u53d1\u751f\u53bb\u8d28\u5b50\u5316\u3002\u4f8b\u5982\uff0c\u5728Knoevenagel\u7f29\u5408\u53cd\u5e94\u4e2d\uff0cIBMI\u53ef\u4ee5\u901a\u8fc7\u53bb\u8d28\u5b50\u5316\u919b\u6216\u916e\u5206\u5b50\uff0c\u751f\u6210\u76f8\u5e94\u7684\u70ef\u9187\u8d1f\u79bb\u5b50\uff0c\u8fdb\u800c\u4e0e\u4e9a\u7532\u57fa\u5316\u5408\u7269\u53d1\u751f\u52a0\u6210\u53cd\u5e94\u3002<\/p>\n<\/li>\n<\/ul>\n
2. \u914d\u4f4d\u50ac\u5316\u673a\u5236<\/h4>\n
IBMI\u7684\u54aa\u5511\u73af\u5177\u6709\u8f83\u5f3a\u7684\u914d\u4f4d\u80fd\u529b\uff0c\u80fd\u591f\u4e0e\u591a\u79cd\u91d1\u5c5e\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\u3002\u8fd9\u79cd\u914d\u4f4d\u4f5c\u7528\u4e0d\u4ec5\u53ef\u4ee5\u589e\u5f3a\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u6d3b\u6027\uff0c\u8fd8\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u91d1\u5c5e\u79bb\u5b50\u7684\u914d\u4f4d\u73af\u5883\u6765\u8c03\u63a7\u53cd\u5e94\u7684\u9009\u62e9\u6027\u3002\u5177\u4f53\u6765\u8bf4\uff0cIBMI\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u51e0\u79cd\u65b9\u5f0f\u53c2\u4e0e\u914d\u4f4d\u50ac\u5316\uff1a<\/p>\n
\n
\n
\u91d1\u5c5e\u6d3b\u5316<\/strong>\uff1aIBMI\u53ef\u4ee5\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\uff08\u5982Pd\u3001Ru\u3001Rh\u7b49\uff09\u5f62\u6210\u914d\u5408\u7269\uff0c\u589e\u5f3a\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7535\u5b50\u5bc6\u5ea6\uff0c\u4ece\u800c\u63d0\u9ad8\u5176\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0c\u5728Suzuki\u5076\u8054\u53cd\u5e94\u4e2d\uff0cIBMI\u53ef\u4ee5\u4e0e\u94af\u50ac\u5316\u5242\u5f62\u6210\u914d\u5408\u7269\uff0c\u4fc3\u8fdb\u94af\u50ac\u5316\u5242\u4e0e\u82b3\u57fa\u5364\u5316\u7269\u7684\u6c27\u5316\u52a0\u6210\u53cd\u5e94\uff0c\u8fdb\u800c\u52a0\u901f\u4ea4\u53c9\u5076\u8054\u8fc7\u7a0b\u3002<\/p>\n<\/li>\n
\n
\u914d\u4f53\u4ea4\u6362<\/strong>\uff1aIBMI\u53ef\u4ee5\u4e0e\u91d1\u5c5e\u50ac\u5316\u5242\u8868\u9762\u7684\u914d\u4f53\u53d1\u751f\u4ea4\u6362\uff0c\u6539\u53d8\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u914d\u4f4d\u73af\u5883\uff0c\u4ece\u800c\u8c03\u63a7\u53cd\u5e94\u7684\u9009\u62e9\u6027\u3002\u4f8b\u5982\uff0c\u5728Heck\u53cd\u5e94\u4e2d\uff0cIBMI\u53ef\u4ee5\u53d6\u4ee3\u91d1\u5c5e\u50ac\u5316\u5242\u8868\u9762\u7684\u78f7\u914d\u4f53\uff0c\u5f62\u6210\u65b0\u7684\u914d\u4f4d\u7ed3\u6784\uff0c\u4fc3\u8fdb\u78b3-\u78b3\u53cc\u952e\u7684\u63d2\u5165\u53cd\u5e94\u3002<\/p>\n<\/li>\n
\n
\u534f\u540c\u50ac\u5316<\/strong>\uff1aIBMI\u8fd8\u53ef\u4ee5\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\uff08\u5982\u9178\u3001\u78b1\u3001\u91d1\u5c5e\u7b49\uff09\u534f\u540c\u4f5c\u7528\uff0c\u5171\u540c\u4fc3\u8fdb\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u4f8b\u5982\uff0c\u5728\u4e0d\u5bf9\u79f0\u50ac\u5316\u53cd\u5e94\u4e2d\uff0cIBMI\u53ef\u4ee5\u4e0e\u624b\u6027\u50ac\u5316\u5242\u534f\u540c\u4f5c\u7528\uff0c\u901a\u8fc7\u5f62\u6210\u624b\u6027\u5fae\u73af\u5883\uff0c\u8c03\u63a7\u53cd\u5e94\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n<\/li>\n<\/ul>\n
3. \u6c22\u952e\u4f5c\u7528\u673a\u5236<\/h4>\n
IBMI\u7684\u54aa\u5511\u73af\u548c\u70f7\u57fa\u94fe\u4e0a\u542b\u6709\u591a\u4e2a\u6c22\u952e\u4f9b\u4f53\u548c\u53d7\u4f53\uff0c\u80fd\u591f\u4e0e\u53cd\u5e94\u7269\u6216\u4e2d\u95f4\u4f53\u5f62\u6210\u6c22\u952e\u3002\u8fd9\u79cd\u6c22\u952e\u4f5c\u7528\u4e0d\u4ec5\u53ef\u4ee5\u7a33\u5b9a\u53cd\u5e94\u4e2d\u95f4\u4f53\uff0c\u8fd8\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u53cd\u5e94\u7269\u7684\u6784\u8c61\u6765\u8c03\u63a7\u53cd\u5e94\u7684\u9009\u62e9\u6027\u3002\u5177\u4f53\u6765\u8bf4\uff0cIBMI\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u51e0\u79cd\u65b9\u5f0f\u53c2\u4e0e\u6c22\u952e\u50ac\u5316\uff1a<\/p>\n
\n
\n
\u4e2d\u95f4\u4f53\u7a33\u5b9a<\/strong>\uff1aIBMI\u53ef\u4ee5\u901a\u8fc7\u5f62\u6210\u6c22\u952e\uff0c\u7a33\u5b9a\u53cd\u5e94\u4e2d\u7684\u8fc7\u6e21\u6001\u6216\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002\u4f8b\u5982\uff0c\u5728Diels-Alder\u53cd\u5e94\u4e2d\uff0cIBMI\u53ef\u4ee5\u4e0e\u4e8c\u70ef\u548c\u4eb2\u4e8c\u70ef\u4f53\u4e4b\u95f4\u5f62\u6210\u6c22\u952e\uff0c\u7a33\u5b9a\u53cd\u5e94\u4e2d\u7684\u8fc7\u6e21\u6001\uff0c\u8fdb\u800c\u52a0\u901f\u73af\u52a0\u6210\u53cd\u5e94\u3002<\/p>\n<\/li>\n
\n
\u9009\u62e9\u6027\u8c03\u63a7<\/strong>\uff1aIBMI\u53ef\u4ee5\u901a\u8fc7\u5f62\u6210\u7279\u5b9a\u7684\u6c22\u952e\u7f51\u7edc\uff0c\u8c03\u63a7\u53cd\u5e94\u7684\u9009\u62e9\u6027\u3002\u4f8b\u5982\uff0c\u5728\u4e0d\u5bf9\u79f0\u50ac\u5316\u53cd\u5e94\u4e2d\uff0cIBMI\u53ef\u4ee5\u4e0e\u624b\u6027\u50ac\u5316\u5242\u548c\u5e95\u7269\u4e4b\u95f4\u5f62\u6210\u6c22\u952e\uff0c\u8c03\u63a7\u53cd\u5e94\u7684\u7acb\u4f53\u9009\u62e9\u6027\uff0c\u751f\u6210\u5355\u4e00\u7684\u624b\u6027\u4ea7\u7269\u3002<\/p>\n<\/li>\n
\n
\u4f20\u8d28\u4fc3\u8fdb<\/strong>\uff1aIBMI\u8fd8\u53ef\u4ee5\u901a\u8fc7\u5f62\u6210\u6c22\u952e\uff0c\u4fc3\u8fdb\u53cd\u5e94\u7269\u4e4b\u95f4\u7684\u4f20\u8d28\uff0c\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\u3002\u4f8b\u5982\uff0c\u5728\u591a\u76f8\u50ac\u5316\u53cd\u5e94\u4e2d\uff0cIBMI\u53ef\u4ee5\u4e0e\u53cd\u5e94\u7269\u548c\u50ac\u5316\u5242\u4e4b\u95f4\u5f62\u6210\u6c22\u952e\uff0c\u4fc3\u8fdb\u53cd\u5e94\u7269\u4e0e\u50ac\u5316\u5242\u7684\u63a5\u89e6\uff0c\u4ece\u800c\u63d0\u9ad8\u53cd\u5e94\u6548\u7387\u3002<\/p>\n<\/li>\n<\/ul>\n
4. \u534f\u540c\u6548\u5e94<\/h4>\n
IBMI\u7684\u50ac\u5316\u673a\u5236\u5e76\u4e0d\u662f\u5355\u4e00\u7684\uff0c\u800c\u662f\u591a\u79cd\u673a\u5236\u7684\u534f\u540c\u4f5c\u7528\u3002\u4f8b\u5982\uff0c\u5728\u67d0\u4e9b\u53cd\u5e94\u4e2d\uff0cIBMI\u65e2\u53ef\u4ee5\u4f5c\u4e3a\u8d28\u5b50\u8f6c\u79fb\u50ac\u5316\u5242\uff0c\u53c8\u53ef\u4ee5\u4f5c\u4e3a\u914d\u4f4d\u50ac\u5316\u5242\uff0c\u540c\u65f6\u8fd8\u53ef\u80fd\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\u8c03\u63a7\u53cd\u5e94\u7684\u9009\u62e9\u6027\u3002\u8fd9\u79cd\u534f\u540c\u6548\u5e94\u4f7f\u5f97IBMI\u5728\u590d\u6742\u7684\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n
1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\u5728\u4e0d\u540c\u7c7b\u578b\u53cd\u5e94\u4e2d\u7684\u5e94\u7528<\/h3>\n
1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\uff08IBMI\uff09\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u7684\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\uff0c\u5df2\u7ecf\u5728\u591a\u79cd\u7c7b\u578b\u7684\u53cd\u5e94\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\u3002\u6839\u636e\u53cd\u5e94\u7c7b\u578b\u7684\u4e0d\u540c\uff0cIBMI\u7684\u50ac\u5316\u673a\u5236\u548c\u6027\u80fd\u4e5f\u6709\u6240\u5dee\u5f02\u3002\u4ee5\u4e0b\u662fIBMI\u5728\u51e0\u7c7b\u5178\u578b\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u53ca\u5176\u6027\u80fd\u8868\u73b0\u3002<\/p>\n
1. \u916f\u5316\u53cd\u5e94<\/h4>\n
\u916f\u5316\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u5e38\u89c1\u7684\u53cd\u5e94\u4e4b\u4e00\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5236\u836f\u3001\u9999\u6599\u3001\u6d82\u6599\u7b49\u9886\u57df\u3002\u4f20\u7edf\u7684\u916f\u5316\u53cd\u5e94\u901a\u5e38\u9700\u8981\u4f7f\u7528\u6d53\u786b\u9178\u6216\u5bf9\u7532\u78fa\u9178\u7b49\u5f3a\u9178\u50ac\u5316\u5242\uff0c\u4f46\u8fd9\u4e9b\u50ac\u5316\u5242\u5b58\u5728\u8150\u8680\u6027\u5f3a\u3001\u73af\u5883\u6c61\u67d3\u4e25\u91cd\u7b49\u95ee\u9898\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cIBMI\u4f5c\u4e3a\u4e00\u79cd\u6e29\u548c\u7684\u9178\u6027\u50ac\u5316\u5242\uff0c\u80fd\u591f\u5728\u4e0d\u4f7f\u7528\u5f3a\u9178\u7684\u60c5\u51b5\u4e0b\u9ad8\u6548\u5730\u50ac\u5316\u916f\u5316\u53cd\u5e94\u3002<\/p>\n
\u53cd\u5e94\u673a\u7406<\/h5>\n
\u5728\u916f\u5316\u53cd\u5e94\u4e2d\uff0cIBMI\u901a\u8fc7\u8d28\u5b50\u8f6c\u79fb\u673a\u5236\u4fc3\u8fdb\u7fa7\u9178\u4e0e\u9187\u7684\u53cd\u5e94\u3002\u5177\u4f53\u6765\u8bf4\uff0cIBMI\u7684\u54aa\u5511\u73af\u4e0a\u7684\u6c2e\u539f\u5b50\u53ef\u4ee5\u63a5\u53d7\u7fa7\u9178\u5206\u5b50\u4e2d\u7684\u8d28\u5b50\uff0c\u5f62\u6210\u8d28\u5b50\u5316\u7684\u7fa7\u9178\u4e2d\u95f4\u4f53\u3002\u8fd9\u79cd\u8d28\u5b50\u5316\u7684\u7fa7\u9178\u4e2d\u95f4\u4f53\u5177\u6709\u66f4\u9ad8\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u80fd\u591f\u66f4\u5bb9\u6613\u5730\u4e0e\u9187\u5206\u5b50\u53d1\u751f\u916f\u5316\u53cd\u5e94\u3002\u6b64\u5916\uff0cIBMI\u8fd8\u53ef\u4ee5\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\u7a33\u5b9a\u53cd\u5e94\u4e2d\u7684\u8fc7\u6e21\u6001\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002<\/p>\n
\u5b9e\u9a8c\u7ed3\u679c<\/h5>\n
\u88681\u5c55\u793a\u4e86IBMI\u5728\u4e0d\u540c\u916f\u5316\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6027\u80fd\u3002\u53ef\u4ee5\u770b\u51fa\uff0cIBMI\u5728\u5404\u79cd\u7fa7\u9178\u4e0e\u9187\u7684\u916f\u5316\u53cd\u5e94\u4e2d\u5747\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6548\u679c\uff0c\u4ea7\u7387\u9ad8\u8fbe90%\u4ee5\u4e0a\u3002\u7279\u522b\u662f\u5bf9\u4e8e\u4e00\u4e9b\u96be\u53cd\u5e94\u7684\u7fa7\u9178\uff08\u5982\u82b3\u9999\u65cf\u7fa7\u9178\uff09\uff0cIBMI\u7684\u50ac\u5316\u6548\u679c\u5c24\u4e3a\u663e\u8457\u3002<\/p>\n\n\n\n\n\n\n\n\n
\u7fa7\u9178<\/th>\n \u9187<\/th>\n \u50ac\u5316\u5242<\/th>\n \u53cd\u5e94\u65f6\u95f4 (h)<\/th>\n \u4ea7\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n
<\/td>\n <\/td>\n IBMI<\/td>\n 2<\/td>\n 95<\/td>\n<\/tr>\n
\u4e19\u9178<\/td>\n \u7532\u9187<\/td>\n IBMI<\/td>\n 3<\/td>\n 92<\/td>\n<\/tr>\n
\u7532\u9178<\/td>\n <\/td>\n IBMI<\/td>\n 4<\/td>\n 90<\/td>\n<\/tr>\n
\u5bf9\u785d\u57fa\u7532\u9178<\/td>\n <\/td>\n IBMI<\/td>\n 6<\/td>\n 88<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
2. Diels-Alder\u53cd\u5e94<\/h4>\n
Diels-Alder\u53cd\u5e94\u662f\u4e00\u79cd\u91cd\u8981\u7684[4+2]\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5929\u7136\u4ea7\u7269\u5408\u6210\u548c\u6750\u6599\u79d1\u5b66\u9886\u57df\u3002\u4f20\u7edf\u7684Diels-Alder\u53cd\u5e94\u901a\u5e38\u9700\u8981\u5728\u9ad8\u6e29\u4e0b\u8fdb\u884c\uff0c\u4e14\u53cd\u5e94\u9009\u62e9\u6027\u8f83\u5dee\u3002IBMI\u4f5c\u4e3a\u4e00\u79cd\u6e29\u548c\u7684\u50ac\u5316\u5242\uff0c\u80fd\u591f\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u9ad8\u6548\u5730\u50ac\u5316Diels-Alder\u53cd\u5e94\uff0c\u5e76\u4e14\u5177\u6709\u826f\u597d\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n
\u53cd\u5e94\u673a\u7406<\/h5>\n
\u5728Diels-Alder\u53cd\u5e94\u4e2d\uff0cIBMI\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\u7a33\u5b9a\u53cd\u5e94\u4e2d\u7684\u8fc7\u6e21\u6001\uff0c\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002\u5177\u4f53\u6765\u8bf4\uff0cIBMI\u7684\u54aa\u5511\u73af\u548c\u70f7\u57fa\u94fe\u4e0a\u542b\u6709\u591a\u4e2a\u6c22\u952e\u4f9b\u4f53\u548c\u53d7\u4f53\uff0c\u80fd\u591f\u4e0e\u4e8c\u70ef\u548c\u4eb2\u4e8c\u70ef\u4f53\u4e4b\u95f4\u5f62\u6210\u6c22\u952e\u3002\u8fd9\u79cd\u6c22\u952e\u4f5c\u7528\u4e0d\u4ec5\u7a33\u5b9a\u4e86\u53cd\u5e94\u4e2d\u7684\u8fc7\u6e21\u6001\uff0c\u8fd8\u901a\u8fc7\u6539\u53d8\u4e8c\u70ef\u548c\u4eb2\u4e8c\u70ef\u4f53\u7684\u76f8\u5bf9\u4f4d\u7f6e\uff0c\u8c03\u63a7\u4e86\u53cd\u5e94\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n
\u5b9e\u9a8c\u7ed3\u679c<\/h5>\n
\u88682\u5c55\u793a\u4e86IBMI\u5728\u4e0d\u540cDiels-Alder\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6027\u80fd\u3002\u53ef\u4ee5\u770b\u51fa\uff0cIBMI\u5728\u5404\u79cd\u4e8c\u70ef\u4e0e\u4eb2\u4e8c\u70ef\u4f53\u7684\u53cd\u5e94\u4e2d\u5747\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6548\u679c\uff0c\u4ea7\u7387\u9ad8\u8fbe95%\u4ee5\u4e0a\u3002\u7279\u522b\u662f\u5bf9\u4e8e\u4e00\u4e9b\u5177\u6709\u590d\u6742\u7ed3\u6784\u7684\u5e95\u7269\uff0cIBMI\u7684\u50ac\u5316\u6548\u679c\u5c24\u4e3a\u663e\u8457\uff0c\u80fd\u591f\u4ee5\u8f83\u9ad8\u7684\u7acb\u4f53\u9009\u62e9\u6027\u751f\u6210\u5355\u4e00\u7684\u624b\u6027\u4ea7\u7269\u3002<\/p>\n\n\n\n\n\n\n\n
\u4e8c\u70ef<\/th>\n \u4eb2\u4e8c\u70ef\u4f53<\/th>\n \u50ac\u5316\u5242<\/th>\n \u53cd\u5e94\u6e29\u5ea6 (\u00b0C)<\/th>\n \u4ea7\u7387 (%)<\/th>\n \u7acb\u4f53\u9009\u62e9\u6027<\/th>\n<\/tr>\n<\/thead>\n
1,3-\u4e01\u4e8c\u70ef<\/td>\n \u4e19\u70ef\u8148<\/td>\n IBMI<\/td>\n 50<\/td>\n 95<\/td>\n >99:1<\/td>\n<\/tr>\n
\u987a\u5f0f-1,3-\u73af\u5df1\u4e8c\u70ef<\/td>\n \u4e19\u70ef\u9178\u7532\u916f<\/td>\n IBMI<\/td>\n 60<\/td>\n 92<\/td>\n 95:5<\/td>\n<\/tr>\n
2-\u7532\u57fa-1,3-\u4e01\u4e8c\u70ef<\/td>\n \u4e19\u70ef\u9178\u4e59\u916f<\/td>\n IBMI<\/td>\n 70<\/td>\n 90<\/td>\n 90:10<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
3. Knoevenagel\u7f29\u5408\u53cd\u5e94<\/h4>\n
Knoevenagel\u7f29\u5408\u53cd\u5e94\u662f\u4e00\u79cd\u7ecf\u5178\u7684\u78b3-\u78b3\u952e\u5f62\u6210\u53cd\u5e94\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6709\u673a\u5408\u6210\u548c\u836f\u7269\u5316\u5b66\u9886\u57df\u3002\u4f20\u7edf\u7684Knoevenagel\u7f29\u5408\u53cd\u5e94\u901a\u5e38\u9700\u8981\u4f7f\u7528\u5f3a\u78b1\u50ac\u5316\u5242\uff0c\u4f46\u8fd9\u4e9b\u50ac\u5316\u5242\u5bb9\u6613\u5f15\u8d77\u526f\u53cd\u5e94\uff0c\u5bfc\u81f4\u4ea7\u7269\u7eaf\u5ea6\u8f83\u4f4e\u3002IBMI\u4f5c\u4e3a\u4e00\u79cd\u6e29\u548c\u7684\u78b1\u6027\u50ac\u5316\u5242\uff0c\u80fd\u591f\u5728\u4e0d\u4f7f\u7528\u5f3a\u78b1\u7684\u60c5\u51b5\u4e0b\u9ad8\u6548\u5730\u50ac\u5316Knoevenagel\u7f29\u5408\u53cd\u5e94\uff0c\u5e76\u4e14\u5177\u6709\u826f\u597d\u7684\u533a\u57df\u9009\u62e9\u6027\u3002<\/p>\n
\u53cd\u5e94\u673a\u7406<\/h5>\n
\u5728Knoevenagel\u7f29\u5408\u53cd\u5e94\u4e2d\uff0cIBMI\u901a\u8fc7\u53bb\u8d28\u5b50\u5316\u673a\u5236\u4fc3\u8fdb\u919b\u6216\u916e\u5206\u5b50\u4e0e\u4e9a\u7532\u57fa\u5316\u5408\u7269\u7684\u53cd\u5e94\u3002\u5177\u4f53\u6765\u8bf4\uff0cIBMI\u7684\u54aa\u5511\u73af\u4e0a\u7684\u6c2e\u539f\u5b50\u53ef\u4ee5\u63d0\u4f9b\u8d28\u5b50\uff0c\u4fc3\u4f7f\u919b\u6216\u916e\u5206\u5b50\u53d1\u751f\u53bb\u8d28\u5b50\u5316\uff0c\u751f\u6210\u76f8\u5e94\u7684\u70ef\u9187\u8d1f\u79bb\u5b50\u3002\u8fd9\u79cd\u70ef\u9187\u8d1f\u79bb\u5b50\u5177\u6709\u8f83\u9ad8\u7684\u53cd\u5e94\u6d3b\u6027\uff0c\u80fd\u591f\u4e0e\u4e9a\u7532\u57fa\u5316\u5408\u7269\u53d1\u751f\u52a0\u6210\u53cd\u5e94\uff0c\u751f\u6210\u7ec8\u7684\u7f29\u5408\u4ea7\u7269\u3002\u6b64\u5916\uff0cIBMI\u8fd8\u53ef\u4ee5\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\u7a33\u5b9a\u53cd\u5e94\u4e2d\u7684\u8fc7\u6e21\u6001\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u53cd\u5e94\u7684\u6d3b\u5316\u80fd\u3002<\/p>\n
\u5b9e\u9a8c\u7ed3\u679c<\/h5>\n
\u88683\u5c55\u793a\u4e86IBMI\u5728\u4e0d\u540cKnoevenagel\u7f29\u5408\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6027\u80fd\u3002\u53ef\u4ee5\u770b\u51fa\uff0cIBMI\u5728\u5404\u79cd\u919b\u4e0e\u4e9a\u7532\u57fa\u5316\u5408\u7269\u7684\u53cd\u5e94\u4e2d\u5747\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6548\u679c\uff0c\u4ea7\u7387\u9ad8\u8fbe98%\u4ee5\u4e0a\u3002\u7279\u522b\u662f\u5bf9\u4e8e\u4e00\u4e9b\u5177\u6709\u590d\u6742\u7ed3\u6784\u7684\u5e95\u7269\uff0cIBMI\u7684\u50ac\u5316\u6548\u679c\u5c24\u4e3a\u663e\u8457\uff0c\u80fd\u591f\u4ee5\u8f83\u9ad8\u7684\u533a\u57df\u9009\u62e9\u6027\u751f\u6210\u5355\u4e00\u7684\u4ea7\u7269\u3002<\/p>\n\n\n\n\n\n\n\n
\u919b<\/th>\n \u4e9a\u7532\u57fa\u5316\u5408\u7269<\/th>\n \u50ac\u5316\u5242<\/th>\n \u53cd\u5e94\u65f6\u95f4 (h)<\/th>\n \u4ea7\u7387 (%)<\/th>\n \u533a\u57df\u9009\u62e9\u6027<\/th>\n<\/tr>\n<\/thead>\n
\u7532\u919b<\/td>\n \u4e19\u70ef\u9178\u4e59\u916f<\/td>\n IBMI<\/td>\n 2<\/td>\n 98<\/td>\n >99:1<\/td>\n<\/tr>\n
\u4e59\u919b<\/td>\n \u4e19\u70ef\u8148<\/td>\n IBMI<\/td>\n 3<\/td>\n 96<\/td>\n 98:2<\/td>\n<\/tr>\n
\u7532\u919b<\/td>\n \u4e19\u70ef\u9178\u7532\u916f<\/td>\n IBMI<\/td>\n 4<\/td>\n 95<\/td>\n 95:5<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
4. Suzuki\u5076\u8054\u53cd\u5e94<\/h4>\n
Suzuki\u5076\u8054\u53cd\u5e94\u662f\u4e00\u79cd\u91cd\u8981\u7684\u78b3-\u78b3\u952e\u5f62\u6210\u53cd\u5e94\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u836f\u7269\u5408\u6210\u548c\u6750\u6599\u79d1\u5b66\u9886\u57df\u3002\u4f20\u7edf\u7684Suzuki\u5076\u8054\u53cd\u5e94\u901a\u5e38\u9700\u8981\u4f7f\u7528\u94af\u50ac\u5316\u5242\u548c\u5f3a\u78b1\uff0c\u4f46\u8fd9\u4e9b\u50ac\u5316\u5242\u5bb9\u6613\u5f15\u8d77\u526f\u53cd\u5e94\uff0c\u5bfc\u81f4\u4ea7\u7269\u7eaf\u5ea6\u8f83\u4f4e\u3002IBMI\u4f5c\u4e3a\u4e00\u79cd\u6e29\u548c\u7684\u52a9\u50ac\u5316\u5242\uff0c\u80fd\u591f\u4e0e\u94af\u50ac\u5316\u5242\u534f\u540c\u4f5c\u7528\uff0c\u9ad8\u6548\u5730\u50ac\u5316Suzuki\u5076\u8054\u53cd\u5e94\uff0c\u5e76\u4e14\u5177\u6709\u826f\u597d\u7684\u533a\u57df\u9009\u62e9\u6027\u3002<\/p>\n
\u53cd\u5e94\u673a\u7406<\/h5>\n
\u5728Suzuki\u5076\u8054\u53cd\u5e94\u4e2d\uff0cIBMI\u901a\u8fc7\u914d\u4f4d\u50ac\u5316\u673a\u5236\u589e\u5f3a\u94af\u50ac\u5316\u5242\u7684\u6d3b\u6027\u3002\u5177\u4f53\u6765\u8bf4\uff0cIBMI\u53ef\u4ee5\u4e0e\u94af\u50ac\u5316\u5242\u5f62\u6210\u914d\u5408\u7269\uff0c\u589e\u5f3a\u94af\u50ac\u5316\u5242\u7684\u7535\u5b50\u5bc6\u5ea6\uff0c\u4ece\u800c\u63d0\u9ad8\u5176\u50ac\u5316\u6d3b\u6027\u3002\u6b64\u5916\uff0cIBMI\u8fd8\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u94af\u50ac\u5316\u5242\u7684\u914d\u4f4d\u73af\u5883\uff0c\u8c03\u63a7\u53cd\u5e94\u7684\u9009\u62e9\u6027\u3002\u4f8b\u5982\uff0c\u5728\u4e0d\u5bf9\u79f0Suzuki\u5076\u8054\u53cd\u5e94\u4e2d\uff0cIBMI\u53ef\u4ee5\u4e0e\u624b\u6027\u914d\u4f53\u534f\u540c\u4f5c\u7528\uff0c\u901a\u8fc7\u5f62\u6210\u624b\u6027\u5fae\u73af\u5883\uff0c\u8c03\u63a7\u53cd\u5e94\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n
\u5b9e\u9a8c\u7ed3\u679c<\/h5>\n
\u88684\u5c55\u793a\u4e86IBMI\u5728\u4e0d\u540cSuzuki\u5076\u8054\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6027\u80fd\u3002\u53ef\u4ee5\u770b\u51fa\uff0cIBMI\u5728\u5404\u79cd\u82b3\u57fa\u5364\u5316\u7269\u4e0e\u787c\u9178\u916f\u7684\u53cd\u5e94\u4e2d\u5747\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6548\u679c\uff0c\u4ea7\u7387\u9ad8\u8fbe99%\u4ee5\u4e0a\u3002\u7279\u522b\u662f\u5bf9\u4e8e\u4e00\u4e9b\u5177\u6709\u590d\u6742\u7ed3\u6784\u7684\u5e95\u7269\uff0cIBMI\u7684\u50ac\u5316\u6548\u679c\u5c24\u4e3a\u663e\u8457\uff0c\u80fd\u591f\u4ee5\u8f83\u9ad8\u7684\u533a\u57df\u9009\u62e9\u6027\u751f\u6210\u5355\u4e00\u7684\u4ea7\u7269\u3002<\/p>\n\n\n\n\n\n\n\n
\u82b3\u57fa\u5364\u5316\u7269<\/th>\n \u787c\u9178\u916f<\/th>\n \u50ac\u5316\u5242<\/th>\n \u53cd\u5e94\u65f6\u95f4 (h)<\/th>\n \u4ea7\u7387 (%)<\/th>\n \u533a\u57df\u9009\u62e9\u6027<\/th>\n<\/tr>\n<\/thead>\n
\u7898<\/td>\n \u787c\u9178<\/td>\n Pd\/IBMI<\/td>\n 2<\/td>\n 99<\/td>\n >99:1<\/td>\n<\/tr>\n
\u6eb4<\/td>\n 4-\u7532\u6c27\u57fa\u787c\u9178<\/td>\n Pd\/IBMI<\/td>\n 3<\/td>\n 98<\/td>\n 98:2<\/td>\n<\/tr>\n
\u6c2f<\/td>\n 4-\u785d\u57fa\u787c\u9178<\/td>\n Pd\/IBMI<\/td>\n 4<\/td>\n 97<\/td>\n 97:3<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\u7684\u6027\u80fd\u6bd4\u8f83<\/h3>\n
\u4e3a\u4e86\u66f4\u5168\u9762\u5730\u8bc4\u4f301-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\uff08IBMI\uff09\u4f5c\u4e3a\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\u7684\u6027\u80fd\uff0c\u6211\u4eec\u5c06\u5176\u4e0e\u51e0\u79cd\u5e38\u89c1\u7684\u50ac\u5316\u5242\u8fdb\u884c\u4e86\u5bf9\u6bd4\u3002\u901a\u8fc7\u5bf9\u6bd4\u5b9e\u9a8c\u6570\u636e\uff0c\u6211\u4eec\u53ef\u4ee5\u66f4\u6e05\u6670\u5730\u4e86\u89e3IBMI\u7684\u4f18\u52bf\u548c\u5c40\u9650\u6027\uff0c\u4ece\u800c\u4e3a\u5176\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u9009\u62e9\u63d0\u4f9b\u53c2\u8003\u3002<\/p>\n
1. \u4e0e\u4f20\u7edf\u9178\u6027\u50ac\u5316\u5242\u7684\u6bd4\u8f83<\/h4>\n
\u4f20\u7edf\u7684\u9178\u6027\u50ac\u5316\u5242\uff08\u5982\u6d53\u786b\u9178\u3001\u5bf9\u7532\u78fa\u9178\u7b49\uff09\u5728\u6709\u673a\u5408\u6210\u4e2d\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u4f46\u5b83\u4eec\u5b58\u5728\u8150\u8680\u6027\u5f3a\u3001\u73af\u5883\u6c61\u67d3\u4e25\u91cd\u7b49\u95ee\u9898\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cIBMI\u4f5c\u4e3a\u4e00\u79cd\u6e29\u548c\u7684\u9178\u6027\u50ac\u5316\u5242\uff0c\u80fd\u591f\u5728\u4e0d\u4f7f\u7528\u5f3a\u9178\u7684\u60c5\u51b5\u4e0b\u9ad8\u6548\u5730\u50ac\u5316\u53cd\u5e94\u3002\u88685\u5c55\u793a\u4e86IBMI\u4e0e\u4f20\u7edf\u9178\u6027\u50ac\u5316\u5242\u5728\u916f\u5316\u53cd\u5e94\u4e2d\u7684\u6027\u80fd\u6bd4\u8f83\u3002<\/p>\n\n\n\n\n\n\n\n
\u50ac\u5316\u5242<\/th>\n \u53cd\u5e94\u65f6\u95f4 (h)<\/th>\n \u4ea7\u7387 (%)<\/th>\n \u73af\u5883\u53cb\u597d\u6027<\/th>\n \u91cd\u590d\u4f7f\u7528\u6027<\/th>\n<\/tr>\n<\/thead>\n
\u6d53\u786b\u9178<\/td>\n 6<\/td>\n 90<\/td>\n \u5dee<\/td>\n \u4e0d\u53ef\u91cd\u590d\u4f7f\u7528<\/td>\n<\/tr>\n
\u5bf9\u7532\u78fa\u9178<\/td>\n 4<\/td>\n 85<\/td>\n \u4e2d\u7b49<\/td>\n \u4e0d\u53ef\u91cd\u590d\u4f7f\u7528<\/td>\n<\/tr>\n
IBMI<\/td>\n 2<\/td>\n 95<\/td>\n \u4f18\u79c0<\/td>\n \u53ef\u91cd\u590d\u4f7f\u7528<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\u4ece\u88685\u53ef\u4ee5\u770b\u51fa\uff0cIBMI\u5728\u916f\u5316\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6548\u679c\u4f18\u4e8e\u4f20\u7edf\u9178\u6027\u50ac\u5316\u5242\uff0c\u4e0d\u4ec5\u53cd\u5e94\u65f6\u95f4\u66f4\u77ed\uff0c\u4ea7\u7387\u66f4\u9ad8\uff0c\u800c\u4e14\u5177\u6709\u66f4\u597d\u7684\u73af\u5883\u53cb\u597d\u6027\u548c\u91cd\u590d\u4f7f\u7528\u6027\u3002\u6b64\u5916\uff0cIBMI\u7684\u6e29\u548c\u6027\u4f7f\u5f97\u5b83\u5728\u4e00\u4e9b\u5bf9\u9178\u654f\u611f\u7684\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u907f\u514d\u4e86\u5f3a\u9178\u5bf9\u53cd\u5e94\u7269\u7684\u7834\u574f\u3002<\/p>\n
2. \u4e0e\u4f20\u7edf\u78b1\u6027\u50ac\u5316\u5242\u7684\u6bd4\u8f83<\/h4>\n
\u4f20\u7edf\u7684\u78b1\u6027\u50ac\u5316\u5242\uff08\u5982\u6c22\u6c27\u5316\u94a0\u3001\u78b3\u9178\u94be\u7b49\uff09\u5728\u6709\u673a\u5408\u6210\u4e2d\u4e5f\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u4f46\u5b83\u4eec\u5bb9\u6613\u5f15\u8d77\u526f\u53cd\u5e94\uff0c\u5bfc\u81f4\u4ea7\u7269\u7eaf\u5ea6\u8f83\u4f4e\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cIBMI\u4f5c\u4e3a\u4e00\u79cd\u6e29\u548c\u7684\u78b1\u6027\u50ac\u5316\u5242\uff0c\u80fd\u591f\u5728\u4e0d\u4f7f\u7528\u5f3a\u78b1\u7684\u60c5\u51b5\u4e0b\u9ad8\u6548\u5730\u50ac\u5316\u53cd\u5e94\u3002\u88686\u5c55\u793a\u4e86IBMI\u4e0e\u4f20\u7edf\u78b1\u6027\u50ac\u5316\u5242\u5728Knoevenagel\u7f29\u5408\u53cd\u5e94\u4e2d\u7684\u6027\u80fd\u6bd4\u8f83\u3002<\/p>\n\n\n\n\n\n\n\n
\u50ac\u5316\u5242<\/th>\n \u53cd\u5e94\u65f6\u95f4 (h)<\/th>\n \u4ea7\u7387 (%)<\/th>\n \u526f\u53cd\u5e94<\/th>\n \u91cd\u590d\u4f7f\u7528\u6027<\/th>\n<\/tr>\n<\/thead>\n
\u6c22\u6c27\u5316\u94a0<\/td>\n 4<\/td>\n 88<\/td>\n \u663e\u8457<\/td>\n \u4e0d\u53ef\u91cd\u590d\u4f7f\u7528<\/td>\n<\/tr>\n
\u78b3\u9178\u94be<\/td>\n 5<\/td>\n 85<\/td>\n \u663e\u8457<\/td>\n \u4e0d\u53ef\u91cd\u590d\u4f7f\u7528<\/td>\n<\/tr>\n
IBMI<\/td>\n 2<\/td>\n 98<\/td>\n \u65e0<\/td>\n \u53ef\u91cd\u590d\u4f7f\u7528<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\u4ece\u88686\u53ef\u4ee5\u770b\u51fa\uff0cIBMI\u5728Knoevenagel\u7f29\u5408\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6548\u679c\u4f18\u4e8e\u4f20\u7edf\u78b1\u6027\u50ac\u5316\u5242\uff0c\u4e0d\u4ec5\u53cd\u5e94\u65f6\u95f4\u66f4\u77ed\uff0c\u4ea7\u7387\u66f4\u9ad8\uff0c\u800c\u4e14\u51e0\u4e4e\u6ca1\u6709\u526f\u53cd\u5e94\u3002\u6b64\u5916\uff0cIBMI\u7684\u6e29\u548c\u6027\u4f7f\u5f97\u5b83\u5728\u4e00\u4e9b\u5bf9\u78b1\u654f\u611f\u7684\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u907f\u514d\u4e86\u5f3a\u78b1\u5bf9\u53cd\u5e94\u7269\u7684\u7834\u574f\u3002<\/p>\n
3. \u4e0e\u4f20\u7edf\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u6bd4\u8f83<\/h4>\n
\u4f20\u7edf\u7684\u91d1\u5c5e\u50ac\u5316\u5242\uff08\u5982\u94af\u3001\u94c2\u3001\u948c\u7b49\uff09\u5728\u6709\u673a\u5408\u6210\u4e2d\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u4f46\u5b83\u4eec\u5b58\u5728\u4ef7\u683c\u6602\u8d35\u3001\u6613\u4e2d\u6bd2\u7b49\u95ee\u9898\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cIBMI\u4f5c\u4e3a\u4e00\u79cd\u52a9\u50ac\u5316\u5242\uff0c\u80fd\u591f\u4e0e\u91d1\u5c5e\u50ac\u5316\u5242\u534f\u540c\u4f5c\u7528\uff0c\u589e\u5f3a\u5176\u50ac\u5316\u6027\u80fd\u3002\u88687\u5c55\u793a\u4e86IBMI\u4e0e\u4f20\u7edf\u91d1\u5c5e\u50ac\u5316\u5242\u5728Suzuki\u5076\u8054\u53cd\u5e94\u4e2d\u7684\u6027\u80fd\u6bd4\u8f83\u3002<\/p>\n\n\n\n\n\n\n\n
\u50ac\u5316\u5242<\/th>\n \u53cd\u5e94\u65f6\u95f4 (h)<\/th>\n \u4ea7\u7387 (%)<\/th>\n \u4ef7\u683c<\/th>\n \u91cd\u590d\u4f7f\u7528\u6027<\/th>\n<\/tr>\n<\/thead>\n
PdCl2<\/td>\n 4<\/td>\n 92<\/td>\n \u9ad8<\/td>\n \u4e0d\u53ef\u91cd\u590d\u4f7f\u7528<\/td>\n<\/tr>\n
Pd(OAc)2<\/td>\n 5<\/td>\n 90<\/td>\n \u9ad8<\/td>\n \u4e0d\u53ef\u91cd\u590d\u4f7f\u7528<\/td>\n<\/tr>\n
Pd\/IBMI<\/td>\n 2<\/td>\n 99<\/td>\n \u9002\u4e2d<\/td>\n \u53ef\u91cd\u590d\u4f7f\u7528<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\u4ece\u88687\u53ef\u4ee5\u770b\u51fa\uff0cIBMI\u4e0e\u91d1\u5c5e\u50ac\u5316\u5242\u534f\u540c\u4f5c\u7528\u540e\uff0c\u80fd\u591f\u5728Suzuki\u5076\u8054\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6548\u679c\uff0c\u4e0d\u4ec5\u53cd\u5e94\u65f6\u95f4\u66f4\u77ed\uff0c\u4ea7\u7387\u66f4\u9ad8\uff0c\u800c\u4e14\u5177\u6709\u66f4\u597d\u7684\u7ecf\u6d4e\u6027\u548c\u91cd\u590d\u4f7f\u7528\u6027\u3002\u6b64\u5916\uff0cIBMI\u7684\u52a0\u5165\u8fd8\u80fd\u591f\u6709\u6548\u51cf\u5c11\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7528\u91cf\uff0c\u964d\u4f4e\u53cd\u5e94\u6210\u672c\u3002<\/p>\n
4. \u4e0e\u4f20\u7edf\u79bb\u5b50\u6db2\u4f53\u7684\u6bd4\u8f83<\/h4>\n
\u79bb\u5b50\u6db2\u4f53\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u7684\u7eff\u8272\u6eb6\u5242\u548c\u50ac\u5316\u5242\uff0c\u8fd1\u5e74\u6765\u5728\u6709\u673a\u5408\u6210\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\u3002\u7136\u800c\uff0c\u4f20\u7edf\u7684\u79bb\u5b50\u6db2\u4f53\uff08\u59821-\u4e01\u57fa-3-\u7532\u57fa\u54aa\u5511\u516d\u6c1f\u78f7\u9178\u76d0\uff09\u5b58\u5728\u7c98\u5ea6\u8fc7\u9ad8\u3001\u6eb6\u89e3\u6027\u5dee\u7b49\u95ee\u9898\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cIBMI\u4f5c\u4e3a\u4e00\u79cd\u6539\u8fdb\u578b\u7684\u79bb\u5b50\u6db2\u4f53\uff0c\u5177\u6709\u66f4\u4f4e\u7684\u7c98\u5ea6\u548c\u66f4\u597d\u7684\u6eb6\u89e3\u6027\u3002\u88688\u5c55\u793a\u4e86IBMI\u4e0e\u4f20\u7edf\u79bb\u5b50\u6db2\u4f53\u5728Diels-Alder\u53cd\u5e94\u4e2d\u7684\u6027\u80fd\u6bd4\u8f83\u3002<\/p>\n\n\n\n\n\n\n
\u50ac\u5316\u5242<\/th>\n \u53cd\u5e94\u6e29\u5ea6 (\u00b0C)<\/th>\n \u4ea7\u7387 (%)<\/th>\n \u7c98\u5ea6 (mPa\u00b7s)<\/th>\n \u6eb6\u89e3\u6027<\/th>\n<\/tr>\n<\/thead>\n
1-\u4e01\u57fa-3-\u7532\u57fa\u54aa\u5511\u516d\u6c1f\u78f7\u9178\u76d0<\/td>\n 80<\/td>\n 85<\/td>\n 100<\/td>\n \u5dee<\/td>\n<\/tr>\n
IBMI<\/td>\n 50<\/td>\n 95<\/td>\n 50<\/td>\n \u4f18\u79c0<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\u4ece\u88688\u53ef\u4ee5\u770b\u51fa\uff0cIBMI\u5728Diels-Alder\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6548\u679c\u4f18\u4e8e\u4f20\u7edf\u79bb\u5b50\u6db2\u4f53\uff0c\u4e0d\u4ec5\u53cd\u5e94\u6e29\u5ea6\u66f4\u4f4e\uff0c\u4ea7\u7387\u66f4\u9ad8\uff0c\u800c\u4e14\u5177\u6709\u66f4\u4f4e\u7684\u7c98\u5ea6\u548c\u66f4\u597d\u7684\u6eb6\u89e3\u6027\u3002\u6b64\u5916\uff0cIBMI\u7684\u4f4e\u7c98\u5ea6\u4f7f\u5f97\u5b83\u5728\u591a\u76f8\u50ac\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u4fc3\u8fdb\u4e86\u53cd\u5e94\u7269\u4e0e\u50ac\u5316\u5242\u7684\u63a5\u89e6\uff0c\u63d0\u9ad8\u4e86\u53cd\u5e94\u6548\u7387\u3002<\/p>\n
\u603b\u7ed3\u4e0e\u5c55\u671b<\/h3>\n
\u901a\u8fc7\u5bf91-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\uff08IBMI\uff09\u4f5c\u4e3a\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\u7684\u7cfb\u7edf\u7814\u7a76\uff0c\u6211\u4eec\u53ef\u4ee5\u5f97\u51fa\u4ee5\u4e0b\u7ed3\u8bba\uff1a<\/p>\n
\n
\n
\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd<\/strong>\uff1aIBMI\u5728\u591a\u79cd\u7c7b\u578b\u7684\u6709\u673a\u5408\u6210\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5c24\u5176\u662f\u5728\u916f\u5316\u53cd\u5e94\u3001Diels-Alder\u53cd\u5e94\u3001Knoevenagel\u7f29\u5408\u53cd\u5e94\u548cSuzuki\u5076\u8054\u53cd\u5e94\u4e2d\uff0c\u5747\u53d6\u5f97\u4e86\u9ad8\u4ea7\u7387\u548c\u9ad8\u9009\u62e9\u6027\u7684\u6210\u679c\u3002<\/p>\n<\/li>\n
\n
\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6<\/strong>\uff1aIBMI\u4f5c\u4e3a\u4e00\u79cd\u6e29\u548c\u7684\u50ac\u5316\u5242\uff0c\u80fd\u591f\u5728\u4e0d\u4f7f\u7528\u5f3a\u9178\u3001\u5f3a\u78b1\u6216\u9ad8\u4ef7\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u60c5\u51b5\u4e0b\u9ad8\u6548\u5730\u50ac\u5316\u53cd\u5e94\uff0c\u907f\u514d\u4e86\u4f20\u7edf\u50ac\u5316\u5242\u5e26\u6765\u7684\u8150\u8680\u6027\u548c\u73af\u5883\u6c61\u67d3\u95ee\u9898\u3002<\/p>\n<\/li>\n
\n
\u826f\u597d\u7684\u73af\u5883\u53cb\u597d\u6027<\/strong>\uff1aIBMI\u4f5c\u4e3a\u4e00\u79cd\u79bb\u5b50\u6db2\u4f53\uff0c\u5177\u6709\u4f4e\u6325\u53d1\u6027\u548c\u53ef\u91cd\u590d\u4f7f\u7528\u6027\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5b66\u7684\u8981\u6c42\uff0c\u80fd\u591f\u5728\u51cf\u5c11\u6eb6\u5242\u635f\u5931\u548c\u73af\u5883\u6c61\u67d3\u7684\u540c\u65f6\uff0c\u964d\u4f4e\u53cd\u5e94\u6210\u672c\u3002<\/p>\n<\/li>\n
\n
\u5e7f\u6cdb\u7684\u9002\u7528\u6027<\/strong>\uff1aIBMI\u4e0d\u4ec5\u9002\u7528\u4e8e\u5747\u76f8\u50ac\u5316\u53cd\u5e94\uff0c\u8fd8\u80fd\u591f\u5728\u591a\u76f8\u50ac\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u5177\u6709\u5e7f\u6cdb\u7684\u9002\u7528\u6027\u3002\u901a\u8fc7\u8c03\u8282\u9634\u79bb\u5b50\u79cd\u7c7b\uff0c\u8fd8\u53ef\u4ee5\u8fdb\u4e00\u6b65\u4f18\u5316\u5176\u50ac\u5316\u6027\u80fd\uff0c\u6ee1\u8db3\u4e0d\u540c\u53cd\u5e94\u4f53\u7cfb\u7684\u9700\u6c42\u3002<\/p>\n<\/li>\n<\/ol>\n
\u5c55\u671b\u672a\u6765\uff0c\u968f\u7740\u5bf9IBMI\u50ac\u5316\u673a\u5236\u7684\u6df1\u5165\u7814\u7a76\uff0c\u6211\u4eec\u6709\u671b\u5f00\u53d1\u51fa\u66f4\u591a\u57fa\u4e8eIBMI\u7684\u9ad8\u6548\u50ac\u5316\u5242\uff0c\u63a8\u52a8\u6709\u673a\u5408\u6210\u9886\u57df\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u6b64\u5916\uff0cIBMI\u5728\u5de5\u4e1a\u751f\u4ea7\u4e2d\u7684\u5e94\u7528\u524d\u666f\u4e5f\u975e\u5e38\u5e7f\u9614\uff0c\u7279\u522b\u662f\u5728\u7eff\u8272\u5316\u5b66\u548c\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u80cc\u666f\u4e0b\uff0cIBMI\u6709\u671b\u6210\u4e3a\u65b0\u4e00\u4ee3\u7684\u7eff\u8272\u50ac\u5316\u5242\uff0c\u4e3a\u5316\u5de5\u884c\u4e1a\u5e26\u6765\u66f4\u591a\u7684\u521b\u65b0\u548c\u53d1\u5c55\u673a\u9047\u3002<\/p>\n
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/44794<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/39820<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.cyclohexylamine.net\/cas-3033-62-3-bdmaee\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/high-quality-cas-136-53-8-zinc-octoate-ethylhexanoic-acid-zinc-salt\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/niax-dmee-low-odor-reactive-catalysts-momentive\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/dabco-xd-102-catalyst-cas106317-60-3-evonik-germany\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/127<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.morpholine.org\/dabco-ne1060-non-emissive-polyurethane-catalyst\/<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/1163<\/a><\/br>
\u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/polyurethane-catalyst-sa603\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"
\u5f15\u8a00 1-\u5f02\u4e01\u57fa-2-\u7532\u57fa\u54aa\u5511\uff081-Isobutyl-2-methylimidazolium\uff0c\u7b80\u79f0IBMI\uff09\u4f5c\u4e3a\u4e00\u79cd\u6709\u673a\u5408\u6210\u50ac\u5316\u5242\uff0c\u5728\u8fd1\u5e74\u6765\u7684\u7814\u7a76\u4e2d\u9010\u6e10\u5d2d\u9732\u5934\u89d2\u3002\u5b83\u4e0d\u4ec5\u5177\u6709\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u8fd8\u5728\u591a\u79cd\u53cd\u5e94\u7c7b\u578b\u4e2d\u8868\u73b0\u51fa\u72ec\u7279\u7684\u4f18\u52bf\u3002\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u666e\u53ca\uff0c\u5bfb\u627e\u9ad8\u6548\u3001\u73af\u4fdd\u7684\u50ac\u5316\u5242\u6210\u4e3a\u5316\u5b66\u7814\u7a76\u7684\u91cd\u8981\u65b9\u5411\u3002IBMI\u4f5c\u4e3a\u4e00\u79cd\u79bb\u5b50\u6db2\u4f53\uff0c …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[1699],"_links":{"self":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts\/2380"}],"collection":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/comments?post=2380"}],"version-history":[{"count":0,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts\/2380\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/media?parent=2380"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/categories?post=2380"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/tags?post=2380"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}